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Hemithio-analogues of meisenheimer complexes and sulphide group activation of aromatic substitution by alkoxides
Authors:Marino Cavazza  Gioia Morganti  Antonio Guerriero  Francesco Pietra
Institution:Istituto di Chimica Generale, Università di Pisa, Pisa Italy;Laboratorio di Chimica Organica, Facoltà di Scienze, Libera Università di Trento, Povo - Trento, Italy
Abstract:EtO? in DMSO adds to ethylthiopicrate at C-3 to generate an ephemeral
-adduct which ends into 1-ethylthio-4-ethoxy-2,5-dinitrobenzene, whilst ethyl picrate gives two adducts of attack of EtS? at C-3 or C-1.
Keywords:
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