Enthalpies of transfer from water to methanol of cations complexed with 18-crown-6 |
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Authors: | Michael H. Abraham Angela F. Danil de Namor How Chiong Ling Ronald A. Schulz |
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Affiliation: | Chemistry Department, University of Surrey, Guildford, Surrey, U.K. |
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Abstract: | Enthalpies of transfer from water to methanol have been obtained via a thermochemical cycle for the [M+18C6] complexes where M+ Na+, K+, Rb+, Cs+, and Ag+. Variation of the transfer enthalpy with M+ is small. |
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