Steric and polar effects in free-radical reactions. - An unusual type of azocoupling by free radical decomposition of diazonium salts |
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| Authors: | Attilio Citterio Francesco Minisci Alberto Albinati Sergio Bruckner |
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| Affiliation: | Istituto di Chimica del Politecnico di Milano, P.za L. da Vinci 32, 20133 Milano Italy |
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| Abstract: | ![]()
A new free-radical azocoupling has been accomplished by decomposition of diazonium salts with monoelectronic reducing agents in the presence of 4-methyl-3-penten-2-one. Steric and polar factors are responsible of the unusual behaviour. |
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