Oxidative cyclisation of a tricarbonylcyclohexadieneiron complex using ferric chloride on silica gel |
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| Authors: | Chi Wi Ong Anthony J Pearson |
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| Institution: | University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW U.K. |
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| Abstract: | Treatment of the diene-Fe(CO)3 complex (2) with dehydrated ferric chloride on silica gel support results in oxidative cyclisation of the alcohol function onto the diene ligand to give (3). This contrasts with the normal behaviour of both diene-Fe(CO)3 complexes and alcohols toward ferric chloride. |
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