| 氯代苯分子3d Rydberg态的共振多光子电离光谱研究 |
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| 引用本文： | 张树东,郭文跃.氯代苯分子3d Rydberg态的共振多光子电离光谱研究[J].原子与分子物理学报,1998,15(2):153-158. |
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| 作者姓名： | 张树东 郭文跃 |
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| 作者单位： | 中国科学字安徽光机所激光光谱学开放研究实验室 |
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| 摘 要： | 用共振多光子电离（ＭＰＩ）技术，结合飞行时间质谱（ＴＯＦＭＳ），对氯代苯（Ｃｌ）分子的３ｄＲｙｄｂｅｒｇ态进行了研究。在λ＝（４７３．０ｎｍ～４８３．０ｎｍ）范围内所获得的光离子光谱呈现出明显的可分辨的结构。经分析为３ｄ态的（３＋１）共振多光子电离，光谱结构可能为３ｄ态振动能级的反映，考虑跃迁选律，对这些结构进行了尝试性指认。
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| 关 键 词： | 多光子电离（MPI） 飞行时间质谱（TOFMS） 氯化苯（ΦCl） |
MULTIPHOTON IONIZATION SPECTROSCOPY STUDYOF CHLOROBENZENE IN 3 d RYDBERG STATE |
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| Zhang Shudong,Guo Wenyue,Fang Li,Wei Jie,Zhang Liandi,Zhao Yaping,Jiang Yunyun,Zhang Bing,Cai JieyeLaser Spectral Lab. AnHui Institute of Optics and Fine Mechanics Academia Sinica HeFei.MULTIPHOTON IONIZATION SPECTROSCOPY STUDYOF CHLOROBENZENE IN 3 d RYDBERG STATE[J].Journal of Atomic and Molecular Physics,1998,15(2):153-158. |
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| Authors: | Zhang Shudong Guo Wenyue Fang Li Wei Jie Zhang Liandi Zhao Yaping Jiang Yunyun Zhang Bing Cai JieyeLaser Spectral Lab AnHui Institute of Optics and Fine Mechanics Academia Sinica HeFei |
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| Institution: | Zhang Shudong Guo Wenyue Fang Li Wei Jie Zhang Liandi Zhao Yaping Jiang Yunyun Zhang Bing Cai JieyeLaser Spectral Lab. AnHui Institute of Optics and Fine Mechanics Academia Sinica HeFei 230031 |
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| Abstract: | Resonance Multiphoton Ionization (MPI) technique combined with Time-of-Flying Mass Spectrometer (TOFMS) was used to study the vibrational constructure of chlorobenzene molecular in 3 d Rydberg state. By (3 1) multiphoton ionization process with 3 d Rydberg state in the range of (473.0nm-483.0nm), fifteen possible vibrational levels were tested and assigned attemptly considering transition rules. |
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