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Synthesis of novel pyridocoumarins and benzo-fused 6-azacoumarins
Authors:Evangelia Galariniotou  Demetrios N. Nicolaides
Affiliation:Laboratory of Organic Chemistry, Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece
Abstract:
Benzo[7,8]-fused 6-azacoumarins are prepared from 4-quinolinol by treatment with PPh3 and DMAD, or from 3-formyl-4-quinolinol by Wittig reaction with carbalkoxyalkylidene(triphenyl)phosphoranes. Angular pyridocoumarins are prepared from 8- or 6-quinolinols with PPh3 and DMAD, or from the reactions of 5,6- or 7,8-quinolinediones with carbalkoxymethylene(triphenyl)phosphoranes.
Keywords:Pyridocoumarins   Benzo[7,8]6-azacoumarins   Wittig reaction   PPh3   DMAD
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