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Recent advances in the chemistry of α,β-unsaturated trifluoromethylketones
Authors:Sergey V. Druzhinin [Author Vitae]Author Vitae]  Valentine G. Nenajdenko [Author Vitae]
Affiliation:Moscow State University, Department of Chemistry, Leninskie Gory, Moscow 119992, Russia
Abstract:
Keywords:Ac, acetyl   (R)-Binol, (R)-(+)-1,1&prime  -bi-2-naphthol   COD, 1,5-cyclooctadiene   DABCO, 1,4-diazabicyclo[2.2.2]octane   Dba, dibenzylideneacetone   DBU, 1,8-diazabicyclo[5.4.0]undec-7-ene   DDQ, 2,3-dichloro-5,6-dicyano-1,4-benzoquinone   Dess-Martin reagent, 1,1,1-tris(acetyloxy)-1,1-dihydro-1,2-benziodoxole-3-(1H)-one   DIP-Cl, (-)-B-chlorodiisopinocampheylborane   DME, dimethoxyethane   DMF, N,N-dimethylformamide   DMF-DMA, N,N-dimethylformamide dimethylacetal   DMSO, dimethylsulfoxide   fod, 6,6,7,7,8,8,8-heptafluoro-2,2-dimethyl-3,5-octanedione   LDA, lithium diisopropylamide   LTMP, lithium 2,2,6,6-tetramethylpiperidide   MCPBA, m-chloroperbenzoic acid   MsCl, methanesulfonylchloride   PMB, 4-methoxybenzyl   PPA, polyphosphoric acid   PPTS, pyridinium p-toluenesulfonate   Py, pyridine   TBAF, tetrabutylammonium fluoride   TBS, tert-butyldimethylsilyl   TFA, trifluoroacetic acid   TFAA, trifluoroacetic acid anhydride   Th, thienyl   THP, tetrahydropyranyl   TMSCF3, trimethyl(trifluromethyl)silane   TMSCl, chlorotrimethylsilane   TMSCN, trimethylsilyl cyanide   p-Tol, p-tolyl (4-methylphenyl)   Tos, 4-methylphenylsulfonyl   p-TsOH, p-toluenesulfonic acid
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