Cyclopalladated ferrocenylimine: a highly effective catalyst for the borylation/suzuki coupling reaction |
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| Authors: | Ning Ma |
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| Affiliation: | Department of Chemistry, Henan Key Laboratory of Chemical Biology and Organic Chemistry, Key Laboratory of Applied Chemistry of Henan Universities, Zhengzhou University, Zhengzhou 450052, PR China |
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| Abstract: | ![]()
The cyclopalladated ferrocenylimine was an efficient catalyst for the borylation/Suzuki coupling reaction. The catalytic loading for the reaction containing bromoarenes was 1 mol %. When iodobenzene was used, the catalytic loading was as low as 0.1 mol %. Furthermore, the cyclopalladated ferrocenylimine also exhibited excellent catalytic power in the case of substrates containing electron-donating substituents, with yields reaching 93% or higher. |
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| Keywords: | Cyclopalladated ferrocenylimine Bis(pinacolato)diboron One-pot borylation Suzuki cross-coupling |
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