An unexpected product from attempted reductive etherification of a silyl alcohol with an aldehyde |
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| Authors: | Christopher G.H. White |
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| Affiliation: | Department of Chemistry, UCL, 20, Gordon Street, London WC1H 0AJ, UK |
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| Abstract: | ![]()
Reductive etherification, using BiBr3/Et3SiH, between two modified amino acids, one with a silyl alcohol side chain and one with an aldehyde side chain, gave, not the desired bis-amino acid, but a tetrahydrooxazine, in good yield. |
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| Keywords: | Reductive etherification Cyclic aminal |
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