Eu-activated Ba2Mg(BO3)2 yellow-emitting phosphors for near ultraviolet-based light-emitting diodes |
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| Authors: | Xinguo ZhangLianghao Fei Jianxin ShiManglian Gong |
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| Institution: | Ministry of Education Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-sen University, Guangzhou 510275, China |
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| Abstract: | A series of Eu2+-activated Ba2Mg(BO3)2 yellow phosphors were prepared by a high temperature solid-state reaction. The phosphor emits intense yellow light under near ultraviolet excitation. Large Stokes shift can be attributed to the asymmetric nature of the Eu site and the lack of rigidity in the host. The concentration self-quenching mechanism of Ba2Mg(BO3)2:Eu2+ is d-d interaction and the critical transfer distance is calculated to be about 12.29 Å. Prototype light-emitting diodes were fabricated by coating the Ba2Mg(BO3)2:0.07Eu2+ phosphor onto ∼370 nm-emitting InGaN chips. The LEDs exhibit intense yellow-emitting under a forward bias of 20 mA. The results indicate that Eu2+-activated Ba2Mg(BO3)2 is a candidate as a yellow component for fabrication of near-UV white light-emitting diodes. |
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| Keywords: | Ba2Mg(BO3)2:Eu2+ Phosphor Optical properties LEDs |
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