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Preparation of high‐activity AgBr/Ag3PO4 photocatalyst based on hexadecyltrimethylammonium bromide and mechanism of photocatalytic enhancement
Authors:Limin Song  Tongtong Li  Shujuan Zhang
Institution:1. College of Environment and Chemical Engineering and State Key Laboratory of Hollow‐Fiber Membrane Materials and Membrane Processes, Tianjin Polytechnic University, Tianjin, People's Republic of China;2. College of Science, Tianjin University of Science and Technology, Tianjin, People's Republic of China
Abstract:A high‐activity AgBr/Ag3PO4 heterojunction photocatalyst was synthesized based on hexadecyltrimethylammonium bromide. Its microspheres were characterized using X‐ray diffractometry, transmission electron microscopy and ultraviolet–visible diffuse reflectance spectroscopy. The new photocatalyst with high photocatalytic activity exceptionally outperforms pure Ag3PO4 and AgBr in methyl orange degradation. The enhancement of photocatalytic activity is attributed to the efficient separation of electron–hole pairs. In this photocatalytic reaction, h+ and ?O2? are the main reactive species that induce visible‐light‐driven degradation.
Keywords:AgBr/Ag3PO4  methyl orange  photocatalytic mechanism  photodegradation
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