| Abstract: | Polyester‐based polyurethane/nanosilica composites were prepared via in situ polymerization and investigated by contact angle measurement, transmission electron microscopy (TEM), atomic force microscopy (AFM) and peel testing in an Instron testing machine. The contact angle and surface free energy results show that nanosilica tended to enrich at the interface between nanocomposite polymers and the substrates, TEM indicated that nanosilica particles were evenly dispersed in the bulk and AFM demonstrated that nanoparticles were located at both the surfaces and interfaces of nanocomposite polymers and that the roughness of both the surfaces and interfaces had a decreasing tendency as the nanosilica content increased, as did the adhesion strength between the nanocomposite polymers and substrates. Copyright © 2003 John Wiley & Sons, Ltd. |
