Synthese und Kristallstruktur von [(Me3Si)2BiCu(PMe3)3], dem ersten Komplex mit einer Bismut—Kupfer‐Bindung |
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| Authors: | Dieter Fenske Alexander Rothenberger Stephan Wieber |
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| Abstract: | Synthesis and Crystal Structure of [(Me3Si)2BiCu(PMe3)3] — the First Complex with a Bismuth—Copper Bond The reaction of CuOt Bu with PMe3 and Bi(SiMe3)3 in hexane yields the phosphine‐stabilized complex [(Me3Si)2Bi‐Cu( PMe3)3]. This synthesis gave rise to the first binuclear Bi—Cu compound to be structurally characterized by X‐ray crystallography. |
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| Keywords: | Copper Bismuth Cluster Crystal structure |
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