| 含有1,4,7-三苄基-1,4,7-三氮杂环壬烷的两个双核铜配合物的合成、表征及其与DNA的相互作用 |
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| 引用本文： | 杨永生,李玉广,琚海燕,阎世平. 含有1,4,7-三苄基-1,4,7-三氮杂环壬烷的两个双核铜配合物的合成、表征及其与DNA的相互作用[J]. 无机化学学报, 2013, 29(18) |
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| 作者姓名： | 杨永生 李玉广 琚海燕 阎世平 |
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| 作者单位： | 武汉纺织大学化学与化工学院, 生物质纤维及生态染整湖北省重点实验室, 武汉 430073,武汉纺织大学化学与化工学院, 生物质纤维及生态染整湖北省重点实验室, 武汉 430073,武汉纺织大学化学与化工学院, 生物质纤维及生态染整湖北省重点实验室, 武汉 430073,南开大学化学系, 天津 300071 |
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| 基金项目： | 武汉纺织大学科技创新计划基金（No.017/165006）和湖北省自然科学基金（No.2016CFB334）资助项目。 |
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| 摘 要： | 合成了2个含有1，4，7-三苄基-1，4，7-三氮杂环壬烷（Bn3tacn）的双核铜配合物：[Cu2（Bn3tacn）2（m-bdc）（CH3CN）3（H2O）2]ClO4（1）和[Cu2（Bn3tacn）2（OH）2]（ClO4）2（2）。配合物1由间苯二甲酸采取单双齿方式桥连Cu（Ⅱ）离子，配合物2由OH桥连。配合物1和2晶体均属于单斜晶系，分别为P21/c空间群和C2/c空间群。分别对2个配合物进行了红外光谱、紫外-可见光谱和元素分析表征。研究了配合物1与DNA的相互作用，对配合物2进行了循环伏安测试。
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| 关 键 词： | 双核铜配合物 1,4,7-三氮杂环壬烷 DNA相互作用 |
| 收稿时间： | 2016-11-21 |
| 修稿时间： | 2017-10-15 |
Synthesis and Characterization of Two Binuclear Copper (II) Complexes Containing 1,4,7-Trisbenzyl-1,4,7-triazacyclononane (Bn3tacn) Ligand and Cleavage Properties with DNAYong-Sheng Yanga,b*, Shi-Ping Yanb* |
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| YANG Yong-Sheng,LI Yu-Guang,JU Hai-Yan and YAN Shi-Ping. Synthesis and Characterization of Two Binuclear Copper (II) Complexes Containing 1,4,7-Trisbenzyl-1,4,7-triazacyclononane (Bn3tacn) Ligand and Cleavage Properties with DNAYong-Sheng Yanga,b*, Shi-Ping Yanb*[J]. Chinese Journal of Inorganic Chemistry, 2013, 29(18) |
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| Authors: | YANG Yong-Sheng LI Yu-Guang JU Hai-Yan YAN Shi-Ping |
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| Affiliation: | Hubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Engineering, Wuhan Textile University, Wuhan 430073, China,Hubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Engineering, Wuhan Textile University, Wuhan 430073, China,Hubei Key Laboratory of Biomass Fiber and Ecological Dyeing and Finishing, School of Chemistry and Engineering, Wuhan Textile University, Wuhan 430073, China and Department of Chemistry, Nankai University, Tianjin 300071, China |
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| Abstract: | Two binuclear copper (II) complexes were prepared with ligand 1,4,7-trisbenzyl-1,4,7-triazacyclononane (Bn3tacn): [Cu2(Bn3tacn)2(m-bdc)(CH3CN)3.2(H2O)](ClO4) (1) and [Cu2(Bn3tacn)2(OH)2.25](H2O)1.25(ClO4)1.75 (2). The compound 1 was bridged by the m-Benedicarboxylic acid (m-bdc) and compound 2 was bridged by the (μ-OH). IR, UV-Vis, element analysis, bingding with DNA properties of the complex 1 and cyclic voltammogram of complex 2 have been studied. |
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| Keywords: | Binuclear copper (II) 1 4 7-Triazacyclonoane Binding with DNA |
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