| Abstract: | In the title complex, Ag2Cd(CN)4(C12H12N2)2]·H2O or cis‐Cd{Ag(CN)2}2(5,5′‐dmbpy)2]·H2O, where 5,5′‐dmbpy is 5,5′‐dimethyl‐2,2′‐bipyridyl, the asymmetric unit consists of a discrete neutral Cd{Ag(CN)2}2(5,5′‐dmbpy)2] unit and a solvent water molecule. The CdII cation is coordinated by two bidentate chelate 5,5′‐dmbpy ligands and two monodentate AgI(CN)2]? anions, which are in a cis arrangement around the CdII cation, leading to an octahedral CdN6 geometry. The overall structure is stabilized by a combination of intermolecular hydrogen bonding, and AgI...AgI and π–π interactions, forming a three‐dimensional supramolecular network. |
