Biocatalysis in ionic liquids: markedly enhanced enantioselectivity of lipase |
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Authors: | Kim K W Song B Choi M Y Kim M J |
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Affiliation: | National Research Laboratory of Chirotechnology, Department of Chemistry, Division of Molecular and Life Sciences, Pohang University of Science and Technology, San 31 Hyojadong, Pohang, Kyungbuk 790-784, Korea. |
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Abstract: | [reaction: see text] Lipase-catalyzed transesterifications in ionic liquids proceeded with markedly enhanced enantioselectivity. It was observed that lipases were up to 25 times more enantioselective in ionic liquids than in conventional organic solvents. |
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