Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2-FeCl2 catalyzed cascade cyclization reaction involving a novel acyl rearrangement process |
| |
| Authors: | Jiang Huanfeng Pan Xiaoyan Huang Liangbin Zhao Jian Shi Dabin |
| |
| Institution: | School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China. jianghf@scut.edu.cn |
| |
| Abstract: | We have discovered a novel PdCl(2)-FeCl(2) catalyzed cascade cyclization reaction, which involves a novel acyl rearrangement process. This reaction affords a diverse set of poly-substituted 4H-cyclopentac]furan products. The reaction scope of this cascade process is quite broad and various internal acetylenes can be employed. |
| |
| Keywords: | |
| 本文献已被 PubMed 等数据库收录！ |
