| 5-Hexadecanolide的不对称合成 |
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| 引用本文： | 孙彬,张朝欣,张贵民,李赢,李裕林,彭立增.5-Hexadecanolide的不对称合成[J].中国化学,2005,23(9):1228-1230. |
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| 作者姓名： | 孙彬 张朝欣 张贵民 李赢 李裕林 彭立增 |
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| 作者单位： | [1]National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, Gansu 730000, China [2]Lu＇nan Pharmaceutical Co., Ltd., Linyi, Shandong 276003, China |
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| 基金项目： | Project supported by the National Natural Science Foundation of China （No.20272020）. |
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| 摘 要： | Optically pure S-5-hexadecanolide （1） has been easily prepared from readily available aldehyde 2 and cyclopentanone （3） using L-proline-catalyzed asymmetric aldol reactions as the key step.
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| 关 键 词： | 乙醛 环戊酮 催化作用 化合物 |
| 收稿时间： | 2004-12-08 |
| 修稿时间： | 2004-12-082005-05-11 |
Asymmetric Synthesis of 5-Hexadecanolide |
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| SUN Bin,ZHANG Chao-Xin,ZHANG Gui-Min,LI Ying,LI Yu-Lin,PENG Li-Zeng.Asymmetric Synthesis of 5-Hexadecanolide[J].Chinese Journal of Chemistry,2005,23(9):1228-1230. |
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| Authors: | SUN Bin ZHANG Chao-Xin ZHANG Gui-Min LI Ying LI Yu-Lin PENG Li-Zeng |
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| Abstract: | Optically pure S‐5‐hexadecanolide ( 1 ) has been easily prepared from readily available aldehyde 2 and cyclopentanone ( 3 ) using L‐proline‐catalyzed asymmetric aldol reactions as the key step. |
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| Keywords: | 5-hexadecanolide Baeyer-Villiger oxidation aldol reaction L-proline |
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