Allylic phosphinates via palladium-catalyzed allylation of H-phosphinic acids with allylic alcohols |
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Authors: | Coudray Laëtitia Bravo-Altamirano Karla Montchamp Jean-Luc |
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Affiliation: | Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA. |
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Abstract: | A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids. |
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