| 含有联苯咔唑的富勒烯C60/C70衍生物的合成、 电化学性质和双光子吸收研究 |
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| 引用本文： | 龚红卫,曾和平,Heping.含有联苯咔唑的富勒烯C60/C70衍生物的合成、 电化学性质和双光子吸收研究[J].有机化学,2009,29(9):1376-1380. |
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| 作者姓名： | 龚红卫 曾和平 Heping |
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| 作者单位： | 华南理工大学化学与化工学院,广州,510641 |
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| 基金项目： | 国家自然科学基金，广东省科技 |
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| 摘 要： | 富勒烯C60/C70与肌氨酸和联苯咔唑醛的1,3-偶极环加成反应, 获得了富勒烯C60/C70-联苯咔唑衍生物3和4, 用1H NMR, 13C NMR, MALDI-TOF-MS表征其结构; 研究了化合物3和4的紫外、荧光和电化学性质; 利用激光光解、Z扫描方法研究其双光子吸收特性.
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| 关 键 词： | 富勒烯 二联苯咔唑 循环伏安法 双光子吸收 |
| 收稿时间： | 2009-2-6 |
| 修稿时间： | 2009-3-13 |
Synthesis, Electrochemical Properties, and Two-photo Absorption of C60/C70 Derivatives Containing 4,4'-Di(9-carbazolyl)biphenyl |
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| Gong,Hongwei Zeng,Heping.Synthesis, Electrochemical Properties, and Two-photo Absorption of C60/C70 Derivatives Containing 4,4'-Di(9-carbazolyl)biphenyl[J].Chinese Journal of Organic Chemistry,2009,29(9):1376-1380. |
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| Authors: | Gong Hongwei Zeng Heping |
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| Institution: | (School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641) |
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| Abstract: | Two novel C60/C70 fullerene derivatives containing 4,4’-di(9-carbazolyl)biphenyl (CBP) unit C60-CBP (3) and C70-CBP (4) have been prepared through 1,3-dipolar cycloaddtion reactions with sarcosine and compound 2. Structures of the target compounds 3 and 4 were characterized by 1H NMR, 13C NMR and MALDI-TOF-MS techniques. The UV-Vis, fluorescence, and cyclic voltammetric analysis and two-photo absorption of the compounds 3 and 4 were discussed in details. |
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| Keywords: | fullerene CBP cyclic voltammetry two-photo absorption |
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