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Investigation of the Fiban K-1 Sulfocationite by the IR Spectroscopy Method
Authors:B. Kh. Cherches  G. N. Lysenko  Yu. G. Egiazarov
Affiliation:(1) Institute of Physical and Organic Chemistry, National Academy of Sciences of Belarus, 13 Surganov Str., Minsk, 220072, Belarus
Abstract:
Using the IR spectroscopy method, we have studied the state of water, sulfogroups, and adsorbed methanol in a Fiban K-1 fibrous cationite under different conditions of preparation of a sample. It is shown that on an air-dried cationite protonation of methanol is performed by the ionic pair [(H2n+1On)+·SO3] after vacuum treatment at 20°C and by the ionic pair [H+·SO3] after vacuum treatment at 90°C.
Keywords:IR spectroscopy  fibrous sulfocationite  state of water  adsorption of methanol  protonation
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