| Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [ NH3 （ CH2 ）2 NH （ CH2 ）2 NH3 ] [ V6 O14 ] |
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| 引用本文： | FU Ping-ping+{1,2},WANG Xin-long+1,WANG En-bo~1**,QIN Chao+1 and XU Lin+11. Institute of Polyoxometalate Chemistry,Department of Chemistry,Northeast Normal University,Changchun 130024,P. R. China,2. China-Japan Union Hospital,Jilin University,Changchun 130024,P. R. ChinaReceived Dec.30,2004. Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [ NH3 （ CH2 ）2 NH （ CH2 ）2 NH3 ] [ V6 O14 ][J]. 高等学校化学研究, 2005, 21(5): 509-511 |
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| 作者姓名： | FU Ping-ping+{1 2} WANG Xin-long+1 WANG En-bo~1** QIN Chao+1 and XU Lin+11. Institute of Polyoxometalate Chemistry Department of Chemistry Northeast Normal University Changchun 130024 P. R. China 2. China-Japan Union Hospital Jilin University Changchun 130024 P. R. ChinaReceived Dec.30 2004 |
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| 作者单位： | FU Ping-ping+{1，2}，WANG Xin-long+1，WANG En-bo~1**，QIN Chao+1 and XU Lin+11. Institute of Polyoxometalate Chemistry，Department of Chemistry，Northeast Normal University，Changchun 130024，P. R. China;2. China-Japan Union Hospital，Jilin University，Changchun 130024，P. R. ChinaReceived Dec.30，2004 |
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| 摘 要： | Introduction Over the past decades, polyoxometalates(POMs)have been attracting extensive interestowing to the widerange of their topological properties and potential appli-cations in catalysis, photochemistry, electrochromism,and magnetism[1,2]. Meanwhile, owing to the potentialapplication of polyoxometalaes as anticancer and antivi-ral drugs, their complexes have attracted increasing in-terest of both inorganic chemists and biochemists[3]. Itis well known that polyoxometalates are excellent …
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| 关 键 词： | POMs 多金属氧酸盐 氧化钒 水晶结构 结构表征 合成工艺 生物活性 |
| 文章编号： | 1005-9040（2005）-05-509-03 |
| 收稿时间： | 2004-12-30 |
Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH3(CH2)2NH(CH2)2NH3][V6O14] |
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| FU Ping-ping,WANG Xin-long,WANG En-bo,QIN Chao,XU Lin. Synthesis, Structure Characterization and Biological Activity of Layered Vanadium Oxides [NH3(CH2)2NH(CH2)2NH3][V6O14][J]. Chemical Research in Chinese University, 2005, 21(5): 509-511 |
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| Authors: | FU Ping-ping WANG Xin-long WANG En-bo QIN Chao XU Lin |
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| Affiliation: | 1. Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China;
2. China-Japan Union Hospital, Jilin University, Changchun 130024, P. R. China |
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| Abstract: | A new layered vanadium oxide [NH3(CH2)2NH(CH2)2NH3][V6O14](compound 1) was synthesized and characterized by elemental analysis, IR spectrometry and single crystal X ray diffraction. The compound crystallizes in a monoclinic space group P2(1)/n with a=1.0254(2) nm, b=0.6739(2) nm, c=1.2400(2) nm, β=93.88(3)°, V=0.8549(3) nm3, Z=2, R1=0.0366, wR2=0.1038. Compound 1 consists of two-dimensional mixed-valence vanadium oxide layers parallelling to the bc plane. The anti-tumor activity of the compound was estimated in three human tumor cell lines in vitro. |
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| Keywords: | Polyoxometalate Vanadium oxide Crystal structure Anti-tumor activity |
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