Calculation of electrostatic interaction forces between ellipsoidal particles |
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Authors: | P. Belouschek D. Lorenz Z. Adamczyk |
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Affiliation: | (1) Institute of Physical Chemistry of the University of Essen-GH, Essen, FRG;(2) Institute of Catalysis and Surface Chemistry of the Polish Academy of Science, Krakow, Poland;(3) Present address: Forschungsstelle Umweltchemie, Universität Essen, Postfach 10 3764, 4300 Essen 1, FRG |
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Abstract: | An analytical expression is presented for describing the electrostatic interaction forces between various shaped particles having mutual orientations. The expression is derived by applying the surface integration method, which is a generalization of the Derjaguin summation procedure. Based on previous theoretical considerations it is possible to calculate the electrostatic interaction force between regularly shaped bodies (both convex or concave in the vicinity of their contact point) by multiplying the interaction energy derived for paralled plates with the corresponding geometric factor. The forces acting between two equal shaped ellipsoids are described and discussed, considering three different limiting orientations, the parallel, the perpendicular, and the contact of the edges' orientation. |
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Keywords: | Electrostatic interaction forces geometrical aspects ellipsoidal particles electrostatic interactions of |
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