Synthesis,IR Spectrum,Thermal Analysis,and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN)2(CN)2]n |
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| Authors: | Güne? Süheyla Kürkçüo?lu Dr Okan Zafer Ye?ilel Ilkan Kavlak Orhan Büyükgüngör |
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| Institution: | 1. Faculty of Arts and Science, Department of Physics, Eski?ehir Osmangazi University, Eski?ehir, Turkey;2. Department of Chemistry, Eski?ehir Osmangazi University, Eski?ehir, Turkey;3. Ondokuz May?s University, Faculty of Arts and Science, Department of Physics, Samsun, Turkey |
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| Abstract: | The heteronuclear polymeric complex, Zn(teta)Ni(μ‐CN)2(CN)2]n (teta: triethylenetetramine), was synthesized and characterized by elementel analysis, FT‐IR spectroscopy, thermal analysis and single crystal X–ray diffraction techniques. The complex crystallizes in the monoclinic system, space group P21/c and in which the ZnII ion exhibits a distorted octahedral coordination by one tetradentate teta ligand and two bridging cyano groups as a trans position, whereas the NiII ion has square planer coordination and is coordinated by four cyano ligands. The decomposition reaction takes places in the temperature range 30–600 °C in the static air atmosphere. |
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| Keywords: | Cyano‐bridged complex Tetracyanonickelate complex Triethylenetetramine complex |
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