Solvent‐Induced Pseudopolymorphism of a New Dinuclear Oxovanadium(V) Compound Based on 2,6‐Di(hydroxymethyl)‐4‐methylphenol |
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| Authors: | Lian Chen Feilong Jiang Mingyan Wu Ning Li Wentao Xu Chunfeng Yan Maochun Hong |
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| Institution: | Key Laboratory of Optoelectronic Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China |
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| Abstract: | Reactions of VO2(acac) (Hacac = acetylacetone) and 2,6‐Di(hydroxymethyl)‐4‐methylphenol (H3L) in different organic solvents give rise to two pseudopolymorphs of a new dinuclear oxovanadium(V) compound, Et3NH]2V2O4(HL)2] ( 1 ) and Et3NH]2V2O4(HL)2]·H2O ( 2 ). The compounds have been synthesized and characterized by elemental analyses, IR spectra and single‐crystal X‐ray diffraction. X‐ray diffraction analyses reveal that 1 and 2 have different weak interactions and display remarkably distinct hydrogen‐bonded networks. |
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| Keywords: | Vanadium Pseudopolymorphism Hydrogen bonds |
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