A Novel μ2‐(H2O)‐Bridged Double‐Chain Coordination Polymer [Cd(pc)(phen)(H2O)]n with Rhombic Grids (H2pc = pamoic acid,phen = 1,10‐phenanthroline) |
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| Authors: | Guang‐Xi Han Yong‐Juan Song Peng‐Cheng Zhao Xia Chen Zheng‐Bo Han Dr |
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| Institution: | 1. College of Chemistry, Liaoning University, Shenyang 110036, P. R. China;2. Department of Forensic Chemistry, China Criminal Police University, Shenyang 110015, P. R. China |
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| Abstract: | A novel coordination polymer Cd(pc)(phen)(H2O)]n (H2pc = pamoic acid, phen = 1,10‐phenanthroline) has been synthesized under hydrothermal conditions. Single crystal X‐ray diffraction analysis reveals that the compound crystallizes in triclinic space group P1. All the CdII atoms in the compound are hexacoordinate and are linked by pamoicate ligands to form a one‐dimensional zigzag chain. Furthermore, two adjacent zigzag chains are connected by the μ2‐(H2O) molecules to form a double‐chain with rhombic grids. There exist intermolecular C–H ··· π contacts, π–π stacking and hydrogen‐bonding interactions. Compound 1 displays strong fluorescent emission in the solid state at room temperature. |
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| Keywords: | Coordination chemistry Polymerizations Cadmium Pamoic acid |
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