Competitive adsorption from multicomponent non-electrolytic liquid mixtures on heterogeneous solid surfaces |
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| Authors: | Anna Derylo-Marczewska M. Jaroniec J. Oscik A. W. Marczewski |
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| Affiliation: | (1) Department of Physical Chemistry, Faculty of Chemistry, M. Curie-Sklodowska University, PL-20031 Lublin, Poland;(2) Department of Chemistry, Kent State University, 44242 Kent, Ohio, USA;(3) Institute of Catalysis and Surface Chemistry of Polish Academy of Sciences (Krakow), Laboratory for Adsorption and Physicochemistry of Interfaces, PL-20031 Lublin, Poland |
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| Abstract: | ![]()
Summary A simple model for competitive adsorption from multicomponent non-electrolytic liquid mixtures on energetically heterogeneous solid surfaces is discussed in terms of statistical thermodynamics. Integral equations are derived for the fundamental thermodynamic quantities that characterize competitive adsorption at the liquid-solid interface. Extensive model studies are presented in order to illustrate the influence of adsorbent heterogeneity on the behaviour of these thermodynamic quantities.on leave from Faculty of Chemistry, M. Curie-Sklodowska University, PL-20031 Lublin, Poland |
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| Keywords: | Adsorbent heterogeneity Adsorption at the liquid-solid interface Adsorption from multicomponent solutions Thermodynamic functions of adsorption |
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