Luminescent silver nanoparticles stabilised by a crown ether capped with an organometallic cluster |
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Authors: | Moawia OE Ahmed |
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Institution: | Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore |
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Abstract: | Monolayer-protected clusters of silver have been synthesised by the NaBH4 reduction of a mixture of silver nitrate and the crown ether (6-mercaptohexyloxy)methyl-15-crown-5, or the triosmium cluster derivative Os3(μ-H)(CO)10(6-mercaptohexyloxy)methyl-15-crown-5]. The nanoparticles showed good stability, are soluble in a wide range of organic solvents, and are luminescent. |
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Keywords: | Osmium Silver Cluster Crown ether Nanoparticles Luminescence |
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