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Luminescent silver nanoparticles stabilised by a crown ether capped with an organometallic cluster
Authors:Moawia OE Ahmed
Institution:Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore
Abstract:Monolayer-protected clusters of silver have been synthesised by the NaBH4 reduction of a mixture of silver nitrate and the crown ether (6-mercaptohexyloxy)methyl-15-crown-5, or the triosmium cluster derivative Os3(μ-H)(CO)10(6-mercaptohexyloxy)methyl-15-crown-5]. The nanoparticles showed good stability, are soluble in a wide range of organic solvents, and are luminescent.
Keywords:Osmium  Silver  Cluster  Crown ether  Nanoparticles  Luminescence
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