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Synthesis and structure of a chiral dinuclear palladium(0) complex with a 30-membered hexaolefinic macrocyclic ligand |
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| Authors: | Anna Pla-Quintana Teodor Parella |
| Affiliation: | a Department of Chemistry, Universitat de Girona, Campus de Montilivi, E-17071 Girona, Spain b Servei de RMN, Universitat Autònoma de Barcelona, Cerdanyola, E-08193 Barcelona, Spain c X-Ray Diffraction Unit, Institute of Chemical Research of Catalonia (ICIQ), Avda. Països Catalans, 16, E-43007 Tarragona, Spain |
| Abstract: | Selective and efficient preparation of a new chiral dipalladium(0) complex with an olefinic macrocyclic ligand named (E,E,E,E,E,E)-1,6,11,16,21,26-hexakis[(4-methylphenyl)sulfonyl]-1,6,11,16,21,26-hexaazacyclotriaconta-3,8,13,18,23,28-hexaenedipalladium(0) (5) is reported. Dinuclear palladium(0) complex 5 has been fully characterized by means of NMR spectroscopy and X-ray diffraction analysis. |
| Keywords: | Palladium Dinuclear complexes Alkene ligands Macrocycles Structural elucidation |
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