Nucleophilic substitution of ferrocenyl alcohols by cerium ammonium nitrate: C-N, C-S, and C-O bonds formation |
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| Authors: | Ran Jiang Shun-Jun Ji |
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| Affiliation: | Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China |
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| Abstract: | Nucleophilic substitution of ferrocenyl alcohols with N-, S-, O-centered nucleophiles promoted by a catalytic amount of cerium ammonium nitrate (CAN) was studied. By this protocol, a series of second arylamine, thioether, and ether were facilely synthesized in moderate to good yields under mild conditions. |
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| Keywords: | Nucleophilic substitution Ferrocenyl alcohol CAN C-X bond formation |
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