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二溴对甲基偶氮羧质子化及其离解
引用本文:黄芳,潘教麦.二溴对甲基偶氮羧质子化及其离解[J].分析化学,1999,27(5):578-581.
作者姓名:黄芳  潘教麦
作者单位:1. 上海纺织高等专科学校纺化系,上海,200051
2. 上海华东师范大学化学系,上海,200062
摘    要:用萃取法对二溴对甲基偶氮羧进行了纯化,并用分光光度法研究了二溴对甲基偶氮羧的质子化和五级离解作用,测定了其质子化常数和逐级离解常数,获得满意的效果。

关 键 词:二溴对甲基偶氮羧  分光光度法  质子化常数  逐级离解常数

The Protonation and Dissociation of Dibromomethyl Carboxyazo
Huang Fang,Pan Jiaomai.The Protonation and Dissociation of Dibromomethyl Carboxyazo[J].Chinese Journal of Analytical Chemistry,1999,27(5):578-581.
Authors:Huang Fang  Pan Jiaomai
Abstract:The protonation and disssociation of dibromomethyl carboxyazo were studied by spectrophotometric method. The protonation constant is lgkp = - 2.50 and the dissociation contants are pk, = 0.40,pk2 = 1.61,pk3 = 2.54, pk4 =9.31 and p45 = 11.44. The purification of dibromomethyl carboxyazo was also described.
Keywords:Dibromomethyl carboxyazo  spectrophotometly  protonation constant  dissociation constant
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