Flow curves of colloidal dispersions close to the glass transition |
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Authors: | Hajnal D Fuchs M |
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Affiliation: | 1.Johannes Gutenberg-Universit?t Mainz,Institut für Physik,Mainz,Germany;2.Universit?t Konstanz,Fachbereich Physik,Konstanz,Germany |
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Abstract: | The flow curves, viz. the curves of stationary stress under steady shearing, are obtained close to the glass transition in dense colloidal dispersions using asymptotic expansions in the schematic -model of mode coupling theory. The shear thinning of the viscosity in fluid states and the yielding of glassy states is discussed. At the transition between fluid and shear-molten glass, simple and generalized Herschel-Bulkley laws are derived with power law exponents that can be computed for different particle interactions from the equilibrium structure factor. |
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Keywords: | KeywordHeading" >PACS 82.70.Dd Colloids 83.50.Ax Steady shear flows, viscometric flow 83.60.Df Nonlinear viscoelasticity 64.70.Q- Theory and modeling of the glass transition |
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