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| （CTAB）_9[Sb_1W_9O_（33）]的制备及其光谱分析 | |
| 引用本文： | 贾太轩,张继昌,石蔚云,宋海香,刘自力.（CTAB）_9[Sb_1W_9O_（33）]的制备及其光谱分析[J].光谱实验室,2011,28(6):2831-2835. |
| 作者姓名： | 贾太轩 张继昌 石蔚云 宋海香 刘自力 |
| 作者单位： | 1. 安阳工学院化学与环境工程学院 河南省安阳市黄河大道55号 455000;广州大学化学化工学院 广州市大学城外环西路230号 510006 2. 安阳工学院化学与环境工程学院 河南省安阳市黄河大道55号 455000 3. 广州大学化学化工学院 广州市大学城外环西路230号 510006 |
| 基金项目： | 国家自然科学基金(20776031); 河南省教育厅教育科学规划课题(2011C530002) |
| 摘 要： | 利用溶胶-凝胶法合成了K9Sb1W9O33],用十六烷基三甲基溴化铵（CTAB）对K9Sb1W9O33]改性,得到了（CTAB）9Sb1W9O33],以过氧化氢氧化环己醇制取环己酮为探针反应,考察了n（Sb）∶n（W）对催化剂催化活性的影响,评价结果表明：催化剂金属原子配比n（Sb）∶n（W）=1∶9,催化活性最高,在该条件下,环己酮的选择性达到了最大值99.2%。通过XRD、FT IR的检测,揭示了（CTAB）9Sb1W9O33]的微观结构和内在规律性,Sb1W9O33]9-与CTAB＋之间存在协同效应,实验结果为工业装置的技术改造提供了较好的实验依据。 |
| 关 键 词： | （CTAB）9[Sb1W9O33] 环己醇 环己酮 催化氧化 |
Preparation of(CTAB)_9[Sb_1W_9O_(33)] and Its Spectral Analysis |
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| JIA Tai-Xuan,ZHANG Ji-Chang,SHI Wei-Yun,SONG Hai-Xiang,LIU Zi-Li.Preparation of(CTAB)_9[Sb_1W_9O_(33)] and Its Spectral Analysis[J].Chinese Journal of Spectroscopy Laboratory,2011,28(6):2831-2835. | |
| Authors: | JIA Tai-Xuan ZHANG Ji-Chang SHI Wei-Yun SONG Hai-Xiang LIU Zi-Li |
| Institution: | JIA Tai-Xuana,b ZHANG Ji-Changa SHI Wei-Yuna SONG Hai-Xianga LIU Zi-Liba(Department of Chemistry & Environmental Engineering,Anyang Institute of Technology,Anyang,Henan 455000,P.R.China)b(College of Chemistry & Chemical Engineering,Guangzhou University,Guangzhou 510006,P.R.China) |
| Abstract: | K9Sb1W9O33] was prepared by sol-gel method.（CTAB）9Sb1W9O33] was obtained by K9Sb1W9O33] modifying cetyltrimethylammonium bromide（CTAB）.The probe reaction of cyclohexanol was oxidized to cyclohexanone by hydrogen peroxide,and the effect of n（Sb）∶n（W） on catalyst activity was investigated.The catalyst evaluation results showed that the optimum catalyst atomic ratio was n（Sb）∶n（W）=1∶9 with high catalytic activity.Under the conditions,the maximum selectivity of cyclohexanone was 99.2%.（CTAB）9Sb1W9O33] was detected by XRD and FTIR.Micro-structure and essence disciplinarian of（CTAB）9Sb1W9O33] were disclosed.Sb1W9O33]9-and CTAB＋ possessed a cooperative effect.The method could provide experimental data for the technical reform of industry equipment. |
| Keywords: | (CTAB)9[Sb1W9O33] Cyclohexanol Cyclohexanone Catalytic Oxidation |
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