Synthesis of 5-alkyl-1,3,5-triazinan-2-ones and 5-alkyl-1,3,5-triazinane-2-thiones using Cu- and Sm-containing catalysts |
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| Authors: | R. R. Khairullina A. R. Geniyatova A. G. Ibragimov U. M. Dzhemilev |
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| Affiliation: | 1359. Institute of Petrochemistry and Catalysis, Russian Academy of Sciences, pr. Oktyabrya 141, Ufa, 450075, Bashkortostan, Russia
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| Abstract: | Efficient procedures have been developed for the synthesis of 5-alkyl-1,3,5-triazinan-2-ones and 5-alkyl-1,3,5-triazinane-2-thiones by reaction of urea (thiourea) with primary alkylamines and N,N,N′,N′-tetramethylmethylenediamine and by reaction of primary amines with N,N′-bis(dimethylaminomethyl)urea(thiourea) in the presence of Cu- and Sm-containing catalysts. |
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