Asymmetric henry reaction catalyzed by chiral schiff base |
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| Authors: | De-qiang Ran Tian-hua Shen Xiao-cong Zhou Jun-qi Li Fu-na Cui Chun-an Ma Qing-bao Song |
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| Institution: | 1350. College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou, 18# Chaowang Road, 310032, P.R.China
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| Abstract: | Four chiral Schiff bases were synthesized conveniently from chiral amino alcohol and 2-hydroxynaphthalene-1-carbaldehyde. These ligands were used to catalyze the addition of nitroalkanes to aldehydes under ambient conditions in good yields with up to 91% ee. |
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