| 导电高聚物聚2，5－二甲基苯胺的化学合成与特性 |
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| 引用本文： | 吴婉群,王月丰.导电高聚物聚2，5－二甲基苯胺的化学合成与特性[J].应用化学,1996(6). |
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| 作者姓名： | 吴婉群 王月丰 |
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| 作者单位： | 西南师范大学化学化工学院 |
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| 摘 要： | 报道了聚２，５－二甲基苯胺（ＰＤＭｅＡｎ）的化学合成，并用标准四探针方法测定其电导率，以ＦＴＩＲ、ＵＶ－Ｖｉｓ吸收光谱、元素分析和ＣＶ法对其性质进行了研究，ＰＤＭｅＡｎ的结构与聚苯胺和聚２，５－二甲氧基苯胺的结构类似，是由其单元通过氮原子（Ｎ）在对位上键合而成，本征态的ＰＤＭｅＡｎ能溶于多种有机溶剂，如ＣＨ２Ｃｌ２、ＣＨＣｌ３、ＤＭＳＯ、ＤＭＦ等。
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| 关 键 词： | 聚二甲基苯胺，导电高聚物，合成，吸收光谱 |
Synthesis and Characteristics of Poly(2,5-dimethylaniline) as Conductive Polymer |
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| Wu Wanqun,Wang Yuefeng.Synthesis and Characteristics of Poly(2,5-dimethylaniline) as Conductive Polymer[J].Chinese Journal of Applied Chemistry,1996(6). |
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| Authors: | Wu Wanqun Wang Yuefeng |
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| Abstract: | Poly(2,5-dimethylaniline)(PDMeAn) powder has been synthesized by chemical method. The electric conductivity of polymer was measured by the method of four standard probes.The polymer was characterized by FTIR,UV-Vis spectroscopy and cyclic voltammetry.The structure of PDMeAn is close to that of polyaniline and poly(2,5-dimethoxyaniline),with monomer units linked through the nitrogen atom at para positions.Intrinsic PDMeAn can be dissolved in a variety of organic solvents(DMF,DMSO,CHCl3,CH2Cl2,etc.).It exhibits excellent environmental stability and electrochemical activity. |
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| Keywords: | poly(dimethylaniline) conductive polymer synthesis absorption spectrum |
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