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Monitoring of Airborne Organic Vapors Using Ion Mobility Spectrometry
Authors:G. A. Eiceman  A. P. Snyder  D. A. Blyth
Affiliation:1. U.S. Army Chemical Research Development and Engineering Center , Aberdeen Proving Ground, MD , 21010-5423;2. Department of Chemistry , New Mexico State University , Las Cruces , NM , 88003;3. U.S. Army Chemical Research Development and Engineering Center , Aberdeen Proving Ground, MD , 21010-5423;4. GeoCenters, Inc , Fort Washington , MD , 20744;5. U.S. Army Chemical Research Development and Engineering Center, SMCCR-RSL , Aberdeen Proving Ground, MD , 21010-5423
Abstract:
Abstract

Automated, continuous monitoring of organic vapors in air under three field designs for plume drift was demonstrated using a hand-held ion mobility spectrometer (IMS) in characterizing IMS behavior as a point sensor. In one field study, the IMS was placed 50cm from a 9m2 grass plot contaminated with methylsalicylate and response to airborne vapors was recorded during a 13hr period of atmospheric turbulence to illustrate susceptibility of point sensors to wind direction. A similar study under near-quiescent atmospheric conditions was made using dimethylsulfoxide. In a third study, the plume from a point source of dipropyleneglycolmonomethylether was interrogated over a 25m × 12m grid downwind with windspeeds of 6–18km h?. Laboratory studies were used to measure instrumental response times and influences from potentially interfering atmospheric organic pollutants.
Keywords:Air monitoring  organic vapors  ion mobility spectrometry
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