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The chemistry of the azanonaborane cluster RNH2---B8H11NHR |
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| Authors: | Detlef Gabel Claudia Bauer Mohamed E El-Zaria Afaf R Genady Udo Drfler |
| Institution: | Department of Chemistry, University of Bremen, PO Box 330440, D-28334, Bremen, Germany |
| Abstract: | The preparation and properties of the R1R2NH---B8H11NHR cluster are described. The cluster is stable to aqueous solutions and can be made water-soluble by the introduction of a few hydrophilic groups. This makes the cluster a good candidate as the boron moiety in compounds for boron neutron capture therapy. The chemistry of the cluster preparation, the stability of the cluster, and conditions for reactions of the organic moieties are reviewed. Pyridine derivatives of the cluster show electronic interaction between the cluster and the pyridine. |
| Keywords: | Azanonaborane Boron neutron capture therapy Cluster rearrangement |
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