Molecular Conductors Based on M(dddt)2 Bisdithiolene Cation Complexes |
| |
| Authors: | EB Yagubskii |
| |
| Institution: | Institute of Problems of Chemical Physics, Chernogolovka, 142432, Moscow District, Russia |
| |
| Abstract: | The synthesis, structure and properties of molecular conductors based on M(dddt)2 cation complexes (dddt = 5,6-dihydro-1,4-dithiin-2,3-dithiolate) which are metal complex analogs of bis(ethylenedithio)tetrathiafulvalene (BEDT-TTF or ET) salts are considered. Formally, the central C=C bond of ET is substituted by a metal ion in the M(dddt)2 complexes. The effect of metal (M=Ni, Pt, Pd) and counterion on crystal structure and conducting properties of M(dddt)2 complexes is analyzed. The similarity and distinction in structures and properties of M(dddt)2 and ET salts are discussed. |
| |
| Keywords: | M(dddt)2 complexes ET salts Structure Conductivity Raman spectra |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
