| 高温空气中NO分子β（B^2ПR—x^2Пr）及γ（A^2∑^＋—X^2Пr … |
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| 引用本文： | 张中明 普小云. 高温空气中NO分子β（B^2ПR—x^2Пr）及γ（A^2∑^＋—X^2Пr …[J]. 光谱学与光谱分析, 1999, 19(3): 274-277 |
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| 作者姓名： | 张中明 普小云 |
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| 摘 要： | 在双原子分子核运动的波动方程中，计入分子的振转相互作用项，得出的波函作与振动量子数有关外，还与转动量子数有关。
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| 关 键 词： | 双原子分子 核运动 波动方程 核波动方程 |
Calculation for Franck-Condon factors of the two band systems beta(B2pi(r) - X2pi(r)) and gamma(A2sigma+ - X2Pi(r)) of NO in the air at high temperature] |
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| Z Zhang,X Pu,L Lin,Y Xiong. Calculation for Franck-Condon factors of the two band systems beta(B2pi(r) - X2pi(r)) and gamma(A2sigma+ - X2Pi(r)) of NO in the air at high temperature][J]. Spectroscopy and Spectral Analysis, 1999, 19(3): 274-277 |
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| Authors: | Z Zhang X Pu L Lin Y Xiong |
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| Affiliation: | Department of Physics, Yunnan University, 650091 Kunming. |
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| Abstract: | From the nuclear Schr?dinger equation of a diatomic molecule with vibration-rotation interaction term involved in it, we derive the wavefunction relevant not only to vibrational quantum number, but also to rotational one. The Franck-Condon factors of the two band systems beta(B2pi(r) - X2pi(r)) and gamma(A2sigma+ - X2Pi(r)) of NO in the air at high temperature are calculated in this paper, using the derived wavefunction. In the calculation, the rotational quantum number J takes values from 0 up to 200. The results apply to both low or high temperature conditions. |
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