| GPC-MALLS技术测定PAMMO的分子量及分子量分布 |
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| 引用本文： | 刘红妮,陈曼,杨彩宁,高朗华,张婷.GPC-MALLS技术测定PAMMO的分子量及分子量分布[J].分析测试技术与仪器,2010,16(1):27-31. |
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| 作者姓名： | 刘红妮 陈曼 杨彩宁 高朗华 张婷 |
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| 作者单位： | 西安近代化学研究所,陕西,西安,710065 |
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| 摘 要： | 采用GPC-多角度激光散射联用技术对PAMMO的分子量及分子量分布进行测定,介绍了方法的测试原理及实验步骤.对实验影响因素如dn/dc、浓度、流速进行了讨论,并对谱图进行了分析.结果表明,dn/dc值为0.0929,浓度为20～60mg/mL,流速为1mL/min,以示差峰的出峰时间和激光峰的收峰时间确定有效峰的条件下,实验获得满意结果.
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| 关 键 词： | 激光光散射法 GPC PAMMO 分子量 分子量分布 |
| 收稿时间： | 2009/10/27 0:00:00 |
| 修稿时间： | 2009/11/26 0:00:00 |
Determination of PAMMO Molecular Weight and Its Distribution by GPC-MALLS Technique |
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| LIU Hong-ni,CHEN Man,YANG Cai-ning,GAO Lang-hua and ZHANG Ting.Determination of PAMMO Molecular Weight and Its Distribution by GPC-MALLS Technique[J].Analysis and Testing Technology and Instruments,2010,16(1):27-31. |
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| Authors: | LIU Hong-ni CHEN Man YANG Cai-ning GAO Lang-hua and ZHANG Ting |
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| Institution: | (Xi′an Modern Chemistry Research Institute,Xi＇an 710065,China) |
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| Abstract: | GPC coupled with multi angle laser light scattering was used to determine molecular weight and distribution of PAMMO. The light scattering principle and procedure was introduced. At the same time some key experimental factors such as dn/dc, concentration, and flow rate were discussed. It is found that when dn/dc is 0.0929, the concentration is 20~60 mg/mL, the flow-rate is 1 mL/min and under the condition that the selection of effective peak area is the occurrence of the differential peak versus the disappearance of laser peak, satisfactory results were obtained. |
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| Keywords: | GPC PAMMO |
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