Microwave-assisted polyol synthesis of carbon-supported platinum-based bimetallic catalysts for ethanol oxidation |
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Authors: | S Stevanovi? D Tripkovi? J Rogan K Popovi? J Lovi? A Tripkovi? V M Jovanovi? |
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Institution: | 1. ICTM, Department of Electrochemistry, University of Belgrade, Njego?eva 12, Belgrade, Serbia 2. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade, Serbia
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Abstract: | High surface area carbon-supported Pt, PtRh, and PtSn catalysts were synthesized by microwave-assisted polyol procedure and tested for ethanol oxidation in perchloric acid. The catalysts were characterized by thermogravimetric analysis (TGA), X-ray diffraction (XRD), scanning tunnelling microscopy (STM), TEM, and EDX techniques. STM analysis of unsupported catalysts shows that small particles (~2?nm) with a narrow size distribution are obtained. TEM and XRD examinations of supported catalysts revealed an increase in particle size upon deposition on carbon support (diameter?~?3?nm). The diffraction peaks of the bimetallic catalysts in X-ray diffraction patterns are slightly shifted to lower (PtSn/C) or higher (PtRh/C) 2θ values with respect to the corresponding peaks at Pt/C catalyst as a consequence of alloy formation. Oxidation of ethanol is significantly improved at PtSn/C with the onset potential shifted for?~?150?mV to more negative values and the increase of activity for approximately three times in comparison to Pt/C catalyst. This is the lowest onset potential found for ethanol oxidation at PtSn catalysts with a similar composition. Chronoamperometric measurements confirmed that PtSn/C is notably less poisoned than Pt/C catalyst. PtRh/C catalyst exhibited mild enhancement of overall electrochemical reaction in comparison to Pt/C. |
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