| 新型大环分子受体: 四同二氧杂杯[6]芳烃衍生物的合成及其络合性质 |
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| 引用本文： | 李海兵,陈远荫,杨祥良.新型大环分子受体: 四同二氧杂杯[6]芳烃衍生物的合成及其络合性质[J].中国化学,2005,23(7):891-894. |
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| 作者姓名： | 李海兵 陈远荫 杨祥良 |
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| 作者单位： | [1]InstituteofMateriaMedica,CollegeofLifeScienceandTechnology,HuazhongUniversityofScienceandTechnology,Wuhan,Hubei430074,China [2]DepartmentofChemistry,WuhanUniversity,Wuhan,Hubei430072,China |
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| 摘 要： | Several tetrahomodioxacalix6]arene hexaesters, hexaacid and hexaamide derivatives were synthesized from tetrahomodioxacalix6]arene by etherification with ethyl bromoacetate. It was found that p-tert-butyltetrahomodioxacalix6]arene hexaethylester exhibited high selectivity towards lithium ion. p-tert-Butyltetrahomodioxacalix6]arene hexaamides showed high ion-binding ability towards transition metal ions.
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| 关 键 词： | 合成 配位性质 大环分子受体 杯[6]芳烃衍生物 离子键 |
| 收稿时间： | 2004-12-8 |
| 修稿时间： | 2005-3-21 |
Syntheses and Complexation Properties of Novel Macrocyclic Molecular Receptors: Tetrahomodioxacalix[6]arene Derivatives |
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| Li Hai‐Bing,Chen Yuan‐Yin,Yang Xiang‐Liang.Syntheses and Complexation Properties of Novel Macrocyclic Molecular Receptors: Tetrahomodioxacalix[6]arene Derivatives[J].Chinese Journal of Chemistry,2005,23(7):891-894. |
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| Authors: | Li Hai‐Bing Chen Yuan‐Yin Yang Xiang‐Liang |
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| Abstract: | Several tetrahomodioxacalix6]arene hexaesters, hexaacid and hexaamide derivatives were synthesized from tetrahomodioxacalix6]arene by etherification with ethyl bromoacetate. It was found that p‐tert‐butyltetrahomodioxacalix6]arene hexaethylester exhibited high selectivity towards lithium ion. p‐tert‐Butyltetrahomodioxacalix6]arene hexaamides showed high ion‐binding ability towards transition metal ions. |
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| Keywords: | calixarene homooxacalixarene ion‐binding |
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