Chiral bisphospholane ligands (Me-ketalphos): synthesis of their Rh(I) complexes and applications in asymmetric hydrogenation |
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| Authors: | Qian Dai |
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| Affiliation: | Department of Chemistry, The Pennsylvania State University, University Park 16802, USA |
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| Abstract: | ![]()
Rhodium complexes of functionalized bisphospholane ligands (S,S,S,S-Me-ketalphos) 1 and (R,S,S,R-Me-ketalphos) 2 have been used as catalyst precursors for the asymmetric hydrogenation of several different types of functionalized olefins and have achieved high enantioselectivities. |
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| Keywords: | Hydrogenation Catalyst Rhodium |
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