New microporous coordination polymer affording guest-coordination sites at channel walls |
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| Authors: | Noro Shin-ichiro Kitagawa Susumu Yamashita Masahiro Wada Tatsuo |
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| Institution: | Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo-ku, Kyoto 606-8501, Japan. |
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| Abstract: | Utilization of a metalloligand, (Cu(2,4-pydca)2(H2O)].2Et3NH) (1) (2,4-pydca = pyridine-2,4-dicarboxylate), as a building unit provides a novel porous coordination polymer, (ZnCu(2,4-pydca)2(H2O)3(DMF)].DMF)n (2), in which the Zn(II) ion at the node of the network acts as a linker and the Cu(II) ion in the channel wall is available for guest-coordination. |
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