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Metastable Ionic Diodes Derived from an Amine‐Based Polymer of Intrinsic Microporosity |
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| Authors: | Dr. Elena Madrid Yuanyang Rong Dr. Mariolino Carta Prof. Neil B. McKeown Richard Malpass‐Evans Prof. Gary A. Attard Tomos J. Clarke Prof. Stuart H. Taylor Prof. Yi‐Tao Long Prof. Frank Marken |
| Affiliation: | 1. Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY (UK);2. School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, EH9 3JJ (UK);3. School of Chemistry, Cardiff University, Cardiff CF10 3AT (UK);4. Shanghai Key Lab of Functional Materials Chemistry & Department of Chemistry, East China University of Science and Technology, Shanghai 200237 (P. R. China) |
| Abstract: | A highly rigid amine‐based polymer of intrinsic microporosity (PIM), prepared by a polymerization reaction involving the formation of Tröger’s base, is demonstrated to act as an ionic diode with electrolyte‐dependent bistable switchable states. |
| Keywords: | diodes fuel cells membranes polymers |