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The formalism of equilibrium quantum statistical mechanics revisited
Authors:Olaf Melsheimer
Institution:(1) Arbeitsgruppe ldquoGrundlagen der Physikrdquo, Fachbereich Physik der Philipps-Universität Marburg, Marburg, West Germany
Abstract:It is shown that the traditional formalism of equilibrium quantum statistical mechanics may fully be incorporated into a general macro-observable approach to quantum statistical mechanics recently proposed by the same author. (1,2) In particular, the partition functions which in the traditional approach are assumed to connect nonnormalized density operators with thermodynamic functions are reinterpreted as functions connecting so-called quantum mechanical effect operators with state parameters. It is argued that these functions although only part of a much richer internal structure of the macro-observable are sufficient to cope with all problems one usually encounters in equilibrium quantum statistical mechanics. p]Denn eigentlich unternehmen wir umsonst, das Wesen eines Dinges auszudrücken. Wirkungen werden wir gewahr, und eine vollständige Geschichte dieser Wirkungen umfaßte wohl allenfalls das Wesen jenes Dinges. Johann W. v. Goethe Farbenlehre
Keywords:
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