Numerical modeling of flow with chemical reactions in a strong shock wave with approximate allowance for translational nonequilibrium

The effect of translational nonequilibrium on the course of chemical reactions in a shock wave is studied using the beam–gas model extended to the case of a multicomponent gas. For Arrhenius reactions of general form with collisions between beam and gas molecules, a modified expression of reaction rate is obtained that takes into account the relative motion of the two media. A procedure for numerical solution of the problem is considered, and calculation results for a shock wave in a dissociating air at an oncoming flow velocity of 6000 m/sec are given.