| 含稀土化合物透明树脂的合成与光学性质 |
| |
| 引用本文： | 王冬梅,刘青云,姜建壮,杨柏.含稀土化合物透明树脂的合成与光学性质[J].发光学报,2009,30(4):427-435. |
| |
| 作者姓名： | 王冬梅 刘青云 姜建壮 杨柏 |
| |
| 作者单位： | 1. 山东大学化学与化工学院 胶体与界面化学教育部重点实验室, 山东 济南 250100;2. 吉林大学化学学院 超分子结构与材料教育部重点实验室, 吉林 长春 130023;3. 山东科技大学 化学与环境工程学院, 山东 青岛 266510 |
| |
| 基金项目： | Supported by the National Natural Science Foundation of China (20171028,20325105,2057104);;the Shandong Postdoc-tor Innovative Project (200703055);;The“Chunlei”Project in SDUST(06540040701)~~ |
| |
| 摘 要： | 我们采用三种不同方法制备了含稀土化合物的光学树脂。第一种是含稀土甲基丙烯酸盐的透明树脂,第二种是采用直接掺杂法制备的含稀土配合物透明树脂,第三种是采用原位复合法制备的含稀土配合物透明树脂。通过对三种透明树脂的热稳定性、抗冲击性、紫外-可见吸收光谱、红外光谱、荧光光谱及核磁等方面的表征,结果表明获得的第二、第三种透明树脂具有非常好的透明性、发光性和相关物理机械性能,进一步比较三种透明树脂的发光性质发现第三种采用原位复合法制备的含稀土配合物透明树脂最好,这说明原位复合法是一种简便快捷合成透明荧光高分子材料的好方法。
|
| 关 键 词： | 透明树脂 稀土 发光性质 复合材料 |
| 收稿时间： | 2008-10-25 |
Synthesis and Optical Properties of Transparent Resins Containing Rare Earth Compounds |
| |
| WANG Dong-mei,LIU Qing-yun,JIANG Jian-zhuang,YANG Bai.Synthesis and Optical Properties of Transparent Resins Containing Rare Earth Compounds[J].Chinese Journal of Luminescence,2009,30(4):427-435. |
| |
| Authors: | WANG Dong-mei LIU Qing-yun JIANG Jian-zhuang YANG Bai |
| |
| Institution: | 1. Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Department of Chemistry, Shandong University, Jinan 250100, China;2. Key Laboratory of Supramolecular Structure and Material of Educational Ministry, College of Chemistry, Jilin University, Changchun 130023, China;3. College of Chemical and Environmental Engineering, Shandong University of Science and Technology, Qingdao 266510, China |
| |
| Abstract: | Three kinds of transparent resins were prepared by three different synthesis methods. Sample 1 is transparent resins formed by RE(MA)3 salt polymerizing,Sample 2 is transparent resins containing rare earth(RE) complexes by doping method,and Sample 3 is transparent resins containing rare earth complexes by in situ compo-site method. The transparent resins were characterized by TGA,impact energy,UV-Vis,FT-IR ,1H-NMR and fluorescence spectra. The fluorescence data indicated that the optical resins display inte... |
| |
| Keywords: | transparent resin rare earth fluorescent property composite materials |
| 本文献已被 CNKI 万方数据 等数据库收录！ |
| 点击此处可从《发光学报》浏览原始摘要信息 |
| 点击此处可从《发光学报》下载免费的PDF全文 |
|
