| A New Chain-like Copper（Ⅱ） Polymer： [Cu（MOPIP）（BDC）]n·0.5n（H2O） |
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| 引用本文： | LIU Boa② ZHOU Shia LI Xiu-Meib LI Chuan-Bia a.A New Chain-like Copper（Ⅱ） Polymer： [Cu（MOPIP）（BDC）]n·0.5n（H2O）[J].结构化学,2008(10):1195-1198. |
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| 作者姓名： | LIU Boa② ZHOU Shia LI Xiu-Meib LI Chuan-Bia a |
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| 作者单位： | Department of Chemistry，Jilin Normal University，Department of Chemistry，Tonghua Teachers College，Tonghua |
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| 基金项目： | The project was supported by the Natural Science Foundation of Jilin Province （No. 2005103） |
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| 摘 要： | A metal-organic coordination compound formulated as Cu（MOPIP）（BDC）]n·0.5n（H2O） 1 （MOPIP - 2-（4-methoxyphenyl）-1H-imidazo4,5-f]1,10] phenanthroline, BDC = 1,4-benze Nedicarboxylate） has been hydrothermally synthesized and structurally characterized by elemental analysis, thermogravimetric analysis, IR spectrum, and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system, space group P1^-, with a = 8.872（5）, b = 11.163（6）, c = 12.589（6）A, α = 94.687（7）, β = 99.930（6）, γ = 103.074（7）°, V = 1186.7（12）A^3, C28H19CuN4O5.5, Mr= 563.01, Dc = 1.576 g/cm^3,μ（MoKa） = 0.973 mm^-1, F（000） = 576, Z = 2, the final R = 0.0607 and wR = 0.1618 for 3419 observed reflections （I 〉 2σ（I））.
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| 关 键 词： | 铜 化合物 晶体结构 MOPIP |
A New Chain-like Copper(Ⅱ) Polymer:[Cu(MOPIP)(BDC)]_n·0.5n(H_2O) |
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| Abstract: | A metal-organic coordination compound formulated as Cu(MOPIP)(BDC)]n·0.5n(H2O) 1 (MOPIP=2-(4-methoxyphenyl)-1H-imidazo4,5-f]1,10] phenanthroline,BDC=1,4-benze Nedicar- boxylate) has been hydrothermally synthesized and structurally characterized by elemental analysis,thermogravimetric analysis,IR spectrum,and single-crystal X-ray diffraction. The title compound crystallizes in the triclinic system,space group P1,with a= 8.872(5),b=11.163(6),c=12.589(6),α=94.687(7),β=99.930(6),γ=103.074(7)°,V=1186.7(12)3,C28H19CuN4O5.5,Mr=563.01,Dc=1.576 g/cm3,μ(MoKα)=0.973 mm-1,F(000)=576,Z=2,the final R=0.0607 and wR=0.1618 for 3419 observed reflections (I>2σ(I)). |
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| Keywords: | copper compound crystal structure MOPIP |
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